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        Ligands which bind weakly to vancomycin : Studies by 13C NMR spectroscopy

        Author
        Pearce, C.M.
        Williams, D.H.
        Gerhard, Ute
        Attention
        2299/11997
        Abstract
        C NMR chemical shifts of vancomycin have been used to obtain the association constants for a number of ligands which bind weakly to the antibiotic. The change in these C chemical shifts upon stepwise addition of ligands provides evidence that the ligands bind in a manner analogous to natural cell-wall precursor analogues. The binding constants obtained are in good agreement with those determined earlier by other methods. Where the ligands are amino acids (glycine or alanine), a potential alkylammonium to amide carbonyl interaction does not promote binding.
        Publication date
        1995-01-01
        Published in
        Journal of the Chemical Society, Perkin Transactions 2
        Other links
        http://hdl.handle.net/2299/11997
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