Synthesis and optical properties of composite films from P3HT and sandwich-like Ag-C-Ag nanoparticles

Yan, Lingpeng, Hao, Yamin, Xiaoting Feng, Xiaoting, Yang, Yongzhen, Liu, Xuguang, Chen, Yong and Xu, Bingshe (2015) Synthesis and optical properties of composite films from P3HT and sandwich-like Ag-C-Ag nanoparticles. RSC Advances, 5 (97). pp. 79860-79867.

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Sandwich-like Ag-C-Ag nanoparticles (Ag-C-Ag NPs) were synthesized under mild hydrothermal conditions in a one-step method. With this approach, Ag was not only encapsulated in the centre of an individual carbon nanosphere, but was also uniformly dispersed within the carbon matrix up to the sphere's shell. Then, poly(3-hexylthiophene):Ag-C-Ag NPs (P3HT:Ag-C-Ag NPs) composite films were prepared by a spin coating method with a chlorobenzene solution of Ag-C-Ag NPs and P3HT. Both morphology and microstructure of Ag-C-Ag NPs were investigated by field emission scanning electron microscopy and high resolution transmission electron microscopy. The possible formation mechanism was proposed. The results have indicated that the Ag-C-Ag NPs present many functional groups and their energy levels match with those of P3HT. It has been observed that an introduction of Ag-C-Ag NPs to P3HT can induce broad and high-absorbing spectra as well as great photoluminescence quenching of P3HT. It is evident that sandwich-like Ag-C-Ag NPs have a great potential to be a new acceptor material in photovoltaic devices.

Item Type	Article
Additional information	This document is the Accepted Manuscript of the following article: Lingpeng Yan, Yamin Hao, Xiaoting Feng, Yongzhen Yang, Xuguang Liu, Yongkang Chen, and Bingshe Xu, ‘Synthesis and optical properties of composite films from P3HT and sandwich-like Ag–C–Ag nanoparticles’, RSC Advances, Vol. 5(97): 79860-79867, 2015, DOI: https://doi.org/10.1039/C5RA16854F. Content in the UH Research Archive is made available for personal research, educational, and non-commercial purposes only. Unless otherwise stated, all content is protected by copyright, and in the absence of an open license, permissions for further re-use should be sought from the publisher, the author, or other copyright holder.
Keywords	sandwich-like ag-c-ag nanoparticles, fabrication, composite film, optical performance
Date Deposited	15 May 2025 13:01
Last Modified	04 Jun 2025 17:03