Thermal cycling and ageing of a glass-ceramic sealant for planar SOFCs

Smeacetto, F., Chrysanthou, A., Salvo, M., Moskalewicz, T., Bytner, F. D'Herin, Ajitdoss, L. C. and Ferraris, M. (2011) Thermal cycling and ageing of a glass-ceramic sealant for planar SOFCs. International Journal of Hydrogen Energy, 36 (18). pp. 11895-11903. ISSN 0360-3199
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Thermal cycling and thermal ageing tests were performed on Crofer22APU/glass-ceramic/Anode-Supported-Electrolyte (ASE) joined samples in air at the SOFC operating temperature of 800 degrees C. The Crofer22APU had been polished and preoxidised at 900 degrees C for 2 h. The diffusion behaviour at the two interfaces was examined and revealed slight diffusion of chromium and manganese from Crofer22APU into the glass-ceramic. No interactions, failure or crack formation were observed at the Crofer22APU/glass-ceramic interface and between the glass-ceramic and YSZ.

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